May 24, 2013

Major advance in generating electricity from wastewater

Improved microbial fuel cell (credit: Oregon State University)

Engineers at Oregon State University have made a breakthrough in the performance of microbial fuel cells that can produce electricity directly from wastewater, opening the door to a future in which waste treatment plants not only will power themselves, but will sell excess electricity.

The new technology developed at OSU uses new concepts — reduced anode-cathode spacing, evolved microbes and new separator materials — and can produce more than two kilowatts per cubic meter of liquid reactor volume — 10 to 50 more times the electrical per unit volume than most other approaches using microbial fuel cells, and 100 times more electricity than some.

This technology cleans sewage by a very different approach than the aerobic bacteria used in the past. Bacteria oxidize the organic matter and, in the process, produce electrons that run from the anode to the cathode within the fuel cell, creating an electrical current.

Almost any type of organic waste material can be used to produce electricity — not only wastewater, but also grass straw, animal waste, and byproducts from such operations as the wine, beer or dairy industries.

The researchers say this could eventually change the way that wastewater is treated all over the world, replacing the widely used “activated sludge” process that has been in use for almost a century. The new approach would produce significant amounts of electricity while effectively cleaning the wastewater, they suggest.

“If this technology works on a commercial scale the way we believe it will, the treatment of wastewater could be a huge energy producer, not a huge energy cost,” said Hong Liu, an associate professor in the OSU Department of Biological and Ecological Engineering. “This could have an impact around the world, save a great deal of money, provide better water treatment and promote energy sustainability.”

Experts estimate that about 3 percent of the electrical energy consumed in the United States and other developed countries is used to treat wastewater, and a majority of that electricity is produced by fossil fuels.

The system also works better than an alternative approach to creating electricity from wastewater that is based on anaerobic digestion that produces methane. It treats the wastewater more effectively, and doesn’t have any of the environmental drawbacks of that technology, such as production of unwanted hydrogen sulfide or possible release of methane, a potent greenhouse gas, the researchers believe.

The OSU system has now been proven at a substantial scale in the laboratory, Liu said, and the next step would be a pilot study. A good candidate, she said, might initially be a food processing plant, which is a contained system that produces a steady supply of certain types of wastewater that would provide significant amounts of electricity.

Once advances are made to reduce high initial costs, researchers estimate that the capital construction costs of this new technology should be comparable to that of the activated sludge systems now in widespread use today — and even less expensive when future sales of excess electricity are factored in.

The approach may also have special value in developing nations, where access to electricity is limited and sewage treatment at remote sites is difficult or impossible as a result.

The ability of microbes to produce electricity has been known for decades, but only recently have technological advances made their production of electricity high enough to be of commercial use. OSU researchers reported several years ago on the promise of this technology, but at that time the systems in use produced far less electrical power.  Continued research should also find even more optimal use of necessary microbes, reduced material costs and improved function of the technology at commercial scales, OSU scientists said.

New storage nanoparticle could make hydrogen a practical fuel

University of New South Wales researchers have demonstrated that hydrogen can be released and reabsorbed from sodium borohydride, a promising storage material, overcoming a major hurdle to i

A diagram of the nanoparticle, with sodium borohydride encased in nickel, and a TEM image of the particles (credit: University of New South Wales)

ts use as an alternative fuel source.

Considered a major a fuel of the future, hydrogen could be used to power buildings, portable electronics and vehicles — but this application hinges on practical storage technology.

The researchers synthesized nanoparticles of sodium borohydride and encased these inside nickel shells.

Their unique “core-shell” nanostructure demonstrated remarkable hydrogen storage properties, including the release of energy at much lower temperatures than previously observed.

“No one has ever tried to synthesize these particles at the nanoscale because they thought it was too difficult, and couldn’t be done. We’re the first to do so, and demonstrate that energy in the form of hydrogen can be stored with sodium borohydride at practical temperatures and pressures,” says Dr Kondo-Francois Aguey-Zinsou from the School of Chemical Engineering at UNSW.

Lightweight compounds known as borohydrides (including lithium and sodium compounds) are known to be effective storage materials, but it was believed that once the energy was released it could not be reabsorbed — a critical limitation. This perceived “irreversibility” means there has been little focus on sodium borohydride.

“By controlling the size and architecture of these structures we can tune their properties and make them reversible — this means they can release and reabsorb hydrogen,” says Aguey-Zinsou. “We now have a way to tap into all these borohydride materials, which are particularly exciting for application on vehicles because of their high hydrogen storage capacity.”

In its bulk form, sodium borohydride requires temperatures above 550 degrees Celsius just to release hydrogen. However, with the core-shell nanostructure, the researchers saw initial energy release happening at just 50 °C, and significant release at 350 °C.

“The new materials that could be generated by this exciting strategy could provide practical solutions to meet many of the energy targets set by the U.S. Department of Energy,” says Aguey-Zinsou.

New solar cells increase solar panel efficiency by more than 25%

New solar cell (credit: University of Cambridge)

University of Cambridge scientists have developed hybrid solar cells that could increase the maximum efficiency of solar panels by more than 25%.

Typically, a solar cell generates a single electron for each photon captured. They added pentacene, an organic semiconductor, to harness the extra energy of blue light, allowing for generating two electrons for every photon from the blue light spectrum. This could enable the cells to capture up to 44% of the incoming solar energy.

Hybrid photovoltaic device architecture. Infrared photons are absorbed using conventional lead sulfide (PbS) nanocrystals. Visible photons are absorbed in pentacene to create singlet excitons, which undergo rapid exciton fission to produce pairs of triplets. (Credit: ACS)

Ref.: Bruno Ehrler, et al., Singlet Exciton Fission-Sensitized Infrared Quantum Dot Solar Cells, NanoLetters, 2012; [DOI:10.1021/nl204297u]